Need Photoshop help

[The_Punisher]

I\'m currently using #12. I tried to set up the transparencies in my Gif Editor, but it came out wrong, with mainly the forehead being clear. My intention was to make the white border outside the circle transparent.

Can anyone help me with this? I\'d like to combine #8 at 10 seconds, with #9 at 1/100 of a second. Plus make the white outside transparent.

Thanks for any help!